Metallopolymer NanocompositesPDF电子书下载
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- 作 者:Pomogailo
- 出 版 社:Springer
- 出版年份:2005
- ISBN:9783540209492
- 页数:563 页
图书介绍: 查看图书目录点击购买PDF全本电子书 上一篇:2010 INTERPRETATION AND APPLICATION OF INTERNATIONAL FINANCIAL REPORTING STANDARDS下一篇:СОВЕРШЕНСТВОВАНИЕ СИСТЕМЫ МАТЕРИАЛЬНОГО ПООЩРЕНИЯ В СТРОИТЕЛЬНЫХ ОРГАНИЗАЦИЯХ 《Metallopolymer Nanocomposites》目录 标签:
Part Ⅰ Structure and Organization of Metal Nanoparticles in Polymer Matrices3
1 Nanoparticles in Materials Chemistry and in the Natural Sciences(Introduction)3
1.1 Classification of Nanoparticles by Size5
1.2 Structural Organization of Nanoparticles9
1.3 Dimensional Phenomena in the Chemistry and Physics of Nanoparticles9
1.4 Nanoparticles and Materials on their Base12
References23
2 Nucleation Mechanism of Nanoparticles and Metal Clusters,their Structure and Chief Properties25
2.1 Characteristic Features of Nanoparticle Nucleation26
2.2 Kinetic Features of New Phase Formation32
2.3 Phase Formation in Chemical Reactions39
2.4 Self-Organization of Metal-Containing Nanoparticles(Fractal Structures)43
2.5 Brief Account of Major Production Methods of Metal-Containing Nanoparticles52
2.6 Metal Clusters as Nanoparticles with Fixed Dimensions58
References60
3 Principles and Mechanisms of Nanoparticle Stabilization by Polymers65
3.1 Stability of Nanoparticles in Solutions65
3.2 Stabilizing Capability Characteristics of Polymers68
3.3 Characteristics of Polymer Absorption on Metal Surfaces71
3.4 Specifics of Polymer Surfactants as Stabilizers81
3.5 Mechanism of Nanoparticle Stabilization by Polymers91
3.6 Stabilization of Nanoparticles by Electrolytes96
3.7 Surface Proofing as a Method of Stabilizing Nanoparticles by Polymers99
3.8 On the Problem of Matrix Confinement101
References106
Part Ⅱ Synthetic Methods for Metallopolymer Nanocomposite Preparation117
4 Physical Methods of Incorporating Nanoparticles into Polymers117
4.1 Mechanochemical Dispersion of Precursors Jointly with Polymers118
4.2 Microencapsulation of Nanoparticles into Polymers120
4.3 Physical Deposition of Metal Particles on Polymers124
4.4 Formation of 2D Nanostructures on Polymers127
4.5 Formation of Metal Nanoparticles in Polymer Matrix Voids(Pores)130
4.6 Physical Modification and Filling of Polymers with Metal131
References132
5 Chemical Methods of Metal-Polymer Nanocomposite Production135
5.1 Reduction of Polymer-Bound Metal Complexes136
5.1.1 Reducers and Reduction Processes136
5.1.2 Reduction in Polymer Solutions138
5.1.3 Reduction in Block-Copolymers in Solution145
5.1.4 Formation and Architecture of Metal Nanoparticles in Dendrimers150
5.1.5 Formation of Nanoparticles in Heterogeneous Polymer Systems155
5.1.6 Production of Nanocomposites by Reducing with Metals and Organometallic Compounds160
5.1.7 Bi- and Polymetallic Nanoparticles in Polymers161
5.2 Nanocomposite Formation by Metal-Containing Precursor Thermolysis172
5.2.1 Metal Sol Formation in Polymers by Thermal Decomposition of Metal Carbonyls173
5.2.2 The Features of Metal-Containing Polymer Thermolysis185
5.2.3 Post-Thermolysis of Other Types of Precursors in Polymer Matrices190
5.3 Nanocomposite Formation in Monomer-Polymer Mixtures in Thermolysis193
5.4 Nanocomposites on the Base of Polymer-Immobilized Metalloclusters196
5.4.1 Monometal-Type Cluster Immobilization196
5.4.2 Heterometallic Clusters,Chemically Bonded with Polymers204
5.4.3 Cluster-Containing Monomer Synthesis and Copolymerization as a Way to Produce Metallopolymeric Composites207
References222
6 Physico-Chemical Methods of Metal-Polymer Nanocomposite Production237
6.1 Cryochemical Methods of Atomic Metal Deposition on Polymers237
6.2 Metal Evaporation Methods on Polymers Localized at Room Temperature246
6.3 Synthesis of Nanocomposites in a Plasma-Chemical Process249
6.4 Radiolysis in Polymer Solutions254
6.5 Photolysis of Metal-Polymer Systems as Means of Obtaining Nanocomposites256
6.6 Electrochemical Methods of Nanocomposite Formation261
References264
Part Ⅲ Hybrid Polymer-Inorganic Nanocomposites273
7 The Sol-Gel Process in Formation of Hybrid Nanocomposites273
7.1 General Characteristics of Sol-Gel Reactions274
7.2 A Combination of Polymerization Reactions and In Situ Sol-Gel Synthesis of Nanocomposites279
7.3 Sol- Gel Syntheses in the Presence of Polymers289
7.4 Morphology and Fractal Model of Hybrid Nanocomposites298
7.5 Nanocomposites Incorporating Multimetallic Ceramics300
References311
8 Polymer Intercalation into Porous and Layered Nanostructures321
8.1 A General Description of the Intercalation Process321
8.2 Polymerization into the Basal(Interlayer)Space327
8.3 The Macromolecules Introducing into the Layered Host Lattices336
8.4 Intercalation Nanocomposites of Polymer/Metal Chalcogenide Type345
8.5 Langmuir-Blodgett Metallopolymer Films as Self-Organized Hybrid Nanocomposites351
References363
9 Nanobiocomposites377
9.1 Basic Notions of Metal-Containing Protein Systems378
9.2 Metal Nanoparticles in Imrnunochemistry,Cytochemistry and Medicine384
9.3 Biosorption,Selective Heterocoagulation and Bacterial Concentration of Metal Nanoparticles390
9.4 Sol-Gel Process as a Way of Ternplate-Synthesized Nanobioceramics399
9.5 Biomineralization and Bioinorganic Nanocomposites403
References415
Part Ⅳ The Main Applications of Metal-Polymeric Nanocomposites427
10 Nanoparticle Modifying Action on Polymers427
10.1 The Control of Physico-Mechanical Properties of Nanocomposites428
10.2 The Peculiarity of Nanocomposites,Synthesized by Sol-Gel Methods431
10.3 Polyolefin-Based Nanocomposites434
10.4 Polymer Matrix Structurization in Nanocomposites437
10.5 The Physical and Mechanical Properties of Metallopolymer Nanocomposites442
10.6 Nanocomposites in Adhesion Compounds(Contacts)and Tribopolymers446
10.7 New Trends in Material Science Connected with Metallopolvmeric Nanocomposites450
References453
11 Magnetic,Electrical and Optical Properties of Metal-Polymer Nanocomposites459
11.1 Metallopolymeric Composites with Magnetic Properties460
11.2 Electrical Characteristics of Metallopolymer Composites473
11.3 Optical and Semiconductive Properties of Metal Polymer Nanosystems486
References501
12 Metallopolymeric Nanocatalysis515
12.1 A General Survey of Metallopolymer Catalysis516
12.2 Hydrogenization Processes517
12.3 Nanocatalysis of Reactions,Traditionally Perfomed with Homogeneous Metallocomplexes532
12.4 Nanocatalysis in Polymerization Processes535
12.5 Polymer-Protected Nanoparticles in Photocatalysis540
12.6 Metallopolymeric Nanocomposites in Catalysis543
References544
13 Conclusion551
Index555
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1、内容概述
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总结:
“Metallopolymer Nanocomposites.pdf电子书版文档下载”是一本关于金属聚合物纳米复合材料的权威著作,内容丰富、结构清晰。通过对该书内容的详细阐述,本文旨在为读者提供全面了解金属聚合物纳米复合材料的知识体系。随着科技的不断发展,金属聚合物纳米复合材料的研究和应用将不断拓展,为人类社会带来更多创新成果。
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