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FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGENPDF电子书下载

外文

• 作 者：RICHARD H.WILEY
• 出 版 社：INTERSCIENCE PUBLISHERS
• 出版年份：2222
• ISBN：
• 页数：493 页

图书介绍： 查看图书目录点击购买PDF全本电子书 上一篇：SELECTED PAPERS ON SILICONE ELASTOMERS VOLUME 2下一篇：PORTABLE C SOFTWARE 《FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGEN》目录 标签：

Part Ⅰ Isoxazoles and Related Compounds＆By Adolfo Quilico1

Introduction1

Nomenclature and Numbering System3

Chapter Ⅰ．Isoxazoles5

Ⅰ．Methods of Preparation of Isoxazoles5

A．Synthesis from 1,3-Dicarbonyl Compounds and Hydroxylamine6

B．Synthesis from α-Acetylenic Ketones and Aldehydes with Hy-droxylamine14

C．Synthesis from Halogenated α,β-Ethylenic Aldehydes or Ke-tones and Hydroxylamine16

D．Isoxazoles from α,β-Unsaturated Ketones and Hydroxylamine16

E．Synthesis from α,β-Dihaloketones and Hydroxylamine16

F．Synthesis from Hydroxamyl Chlorides18

G．Synthesis from Nitrile Oxides19

H．Synthesis with Fulminic Acid and Acetylenic Derivatives22

I．Synthesis from Acetylenic Derivatives and Nitrolic Acids23

J．Synthesis from Primary Nitroparaffins,Nitrostilbenes,and Re-lated Compounds24

K．Synthesis from Unsaturated Compounds and Nitric(Nitrous)Acid27

L．Isoxazoles from Isoxazolines32

M．Other Isoxazole Syntheses33

N．Isoxazoles from Other Heterocycles34

Ⅱ．The Chemical Behavior of Isoxazoles41

A．Basic Properties41

B．Action of Reducing Agents42

C．Oxidation43

D．Action of Alkali,Alkaline Alkoxides,and Other Basic Reagents44

E．Action of Ammonia,Hydroxylamine,Hydrazine,Aromatic Amines,and Hydrazines48

F．Action of Halogens49

G．Action of Chlorosulfonic Acid49

H．Action of Nitric Acid and Mixed Acids50

I．Action of Grignard Reagent50

J．Action of Alkyl Iodides and Sulfates50

Ⅲ．Isoxazole and Its Alkyl and Aryl Derivatives53

A．Isoxazole53

B．Methylisoxazoles54

C．Homologous Alkyl-and Alkenylisoxazoles56

D．Phenylisoxazoles57

E．Homologous Aryl-and Alkylarylisoxazoles59

F．Isoxazoles Containing Heterocyclic Substituents62

Ⅳ．Isoxazole Derivatives66

A．Halogen Derivatives66

B．Nitro Derivatives67

C．Sulfonic Acids70

D．Alcohols,Glycols,and Ethers71

E．Amines73

F．Isoxazoles with Other Nitrogen-Containing Functions75

G．Aldehydes77

H．Ketones79

I．Carboxylic Acids82

J．Amino Acids88

Chapter Ⅱ．Isoxazolines95

Ⅰ．Methods of Preparation of Isoxazolines95

A．From α,β-Unsaturated Ketones and Hydroxylamine96

B．From β-Chloroketones and Hydroxylamine99

C．From Ethylenic Derivatives and Nitrile Oxides99

D．From Isoxazoline N-Oxides102

E．From Quaternary Salts102

Ⅱ．The Chemical Behavior of Isoxazolines102

Ⅲ．Substituted Isoxazolines104

A．Halo Derivatives104

B．Hydroxy Derivatives105

C．Alcohols,Aldehydes,and Ketones105

D．Carboxylic Acids105

E．Stereochemistry of 2-Isoxazolines105

Ⅳ．Isoxazoline N-Oxides111

A．Methods of Preparation111

B．Chemical Behavior of Isoxazoline N-Oxides113

Ⅴ．4,5-Dioxoisoxazolines115

Chapter Ⅲ．Isoxazolones117

Ⅰ．Methods of Preparation of 5-Isoxazolones118

A．Synthesis from β-Ketonic Esters and Hydroxylamine118

B．Synthesis from α-Acetylenic Esters and Hydroxylamine119

C．Synthesis from α,β-Unsaturated Esters and Hydroxylaminc119

D．Synthesis from Sulfur Derivatives of β-Ketonic Esters and Hy-droxylamine119

E．Synthesis with Hydroxamyl Chlorides and Nitrile Oxides120

F．Synthesis from β-Ketonic or α-Acetylenic Esters and Aldoximes121

G．Synthesis from β-Ketonic and α-Acetylenic Nitriles,and Hy-droxylamine121

H．Other Isoxazolone Syntheses121

Ⅱ．The Chemical Behavior of 5-Isoxazolones124

A．Acidic Properties124

B．Action of Reducing Agents126

C．Action of Oxidants126

D．Hydrolytic Cleavage of the Isoxazolone Ring127

E．Action of Halogens127

F．Action of Nitrous Acid128

G．Condensation Reaction with Compounds Containing Carbonyl or Dichloromethyl Groups128

H．Condensation Reactions with Aromatic Nitroso Bases129

I．Coupling with Diazonium Salts129

J．Reactions with Hydrazine Derivatives,Hydroxylamine,and Formamidines130

K．Action of Grignard Reagents130

L．Condensation with Ortho Esters130

Ⅲ．5-Isoxazolones and Their Derivatives132

A．Alkyl-and Aryl-5-lsoxazolones132

B．Unsaturated Isoxazolones132

C．Haloisoxazolones134

D．5-Iminoisoxazolones135

E．Isonitrosoisoxazolones138

F．Nitroisoxazolones139

G．Isoxazolone Azomethines139

H．Azo Derivatives140

I．Alcohols,Aldehydes,Ketones,and Carboxylic Acids of 5-Iso-xazolones142

J．Arylaminomethyleneisoxazolones145

Ⅳ．4-Isoxazolones149

Ⅴ．3-Isoxazolones151

Chapter Ⅳ．Polynuclear Isoxazole Types153

Ⅰ．Biisoxazoles153

A．Synthesis of Biisoxazoles153

B．Properties and Chemical Behavior of Biisoxazoles157

Ⅱ．Biisoxazolines158

Ⅲ．Triisoxazoles and Polyisoxazoles158

Ⅳ．Benzisoxazoles159

A．Indoxazenes160

B．Anthranils166

Ⅴ．Other Polynuclear Condensed Isoxazoles173

A．Naphthoisoxazoles173

B．Anthracene and Anthraquinone Isoxazoles174

C．Other Polynuclear Types175

Chapter Ⅴ．The Physico-Chemical Properties of Isoxazole and Its De-rivatives＆By Giovanni Speroni177

Ⅰ．Isoxazole,Alkyl-and Arylisoxazoles177

Ⅱ．Isoxazolecarboxylic Acids198

Ⅲ．Hydroxyisoxazoles and Isoxazoleamines(Isoxazolones and Isoxa-zolonimides)206

Ⅳ．Benzisoxazoles213

Chapter Ⅵ．Applications of Isoxazole Derivatives223

Ⅰ．Isoxazole Derivatives of Pharmacological Significance223

A．Analeptics223

B．Sulfa Drugs225

C．Other Isoxazole Drugs225

Ⅱ．Other Applications of Isoxazole Derivatives227

Chapter Ⅶ．Isoxazolidines229

Ⅰ．Isoxazolidines229

Ⅱ．Isoxazolidones230

Part Ⅱ Oxadiazoles and Related Compounds＆By Lyell C．Behr233

Chapter Ⅷ．1,2,3-Oxadiazoles235

Ⅰ．The Aliphatic Diazo Compounds235

Ⅱ．The＂Diazophenols＂237

Ⅲ．The Sydnones240

Chapter Ⅸ．1,2,4-Oxadiazoles245

Ⅰ．General245

Ⅱ．Alkyl and Aryl Derivatives245

Ⅲ．Carboxylic Acids and Their Derivatives252

Ⅳ．Alcohols253

Ⅴ．Amino Compounds253

Ⅵ．Hydroxyl Derivatives255

Ⅶ．Acetonyl Compounds257

Ⅷ．Oxadiazolines(Hydrazoximes)258

Ⅸ．Oxadiazolidines259

Chapter Ⅹ．1,3,4-Oxadiazoles263

Ⅰ．General263

Ⅱ．Aryl-1,3,4-oxadiazoles263

Ⅲ．Dialkyl-1,3,4-oxadiazoles264

Ⅳ．Diaryl-and Arylalkyl-l,3,4-oxadiazoles265

Ⅴ．＂Cyclic Azo Compounds＂269

Ⅵ．Amino-l,3,4-oxadiazoles271

Ⅶ．1,3,4-Oxadiazoles with Sulfur-Containing Substituents272

Ⅷ．1,3,4-Oxadiazolines274

Ⅸ．1,3,4-Oxadiazolones274

Ⅹ．Condensed Systems277

Ⅺ．Applications of 1,3,4-Oxadiazoles278

Chapter Ⅺ．Furazans283

Ⅰ．General283

Ⅱ．Furazans284

A．The Dialkylfurazans284

B．Arylfurazans285

C．Diaryl-and Arylalkylfurazans285

D．Hydroxyfurazans287

E．Furazan Ketones287

F．Furazancarboxylic Acids289

G．Aminofurazans291

H．Condensed Furazans292

Ⅲ．Furoxans295

A．Structure295

B．Monosubstituted Furoxans298

C．Dialkylfuroxans298

D．Diaryl-and Arylalkylfuroxans299

E．Carbonyl Compounds302

F．Furoxancarboxylic Acids303

G．Other Substituted Furoxans305

H．Condensed Fuorxans305

Ⅳ．Fulminic Acid Derivatives309

Chapter Ⅻ．Dioxazoles,Dioxadiazoles,and Oxatriazoles321

Ⅰ．Dioxazoles321

Ⅱ．Dioxadiazoles322

Ⅲ．Oxatriazoles323

Part Ⅲ Oxazines and Related Compounds＆By R．L．McKee327

Chapter ⅩⅢ．The 1,2-Oxazines329

Ⅰ．Monocyclic Systems329

Ⅱ．Condensed 1,2-Oxazine Systems335

A．Derivatives of 2,3,1H-Benzoxazine335

B．Derivatives of 1,2,4H-Benzoxazine338

C．Derivatives of Naphth[1,8-de][1,2]oxazine338

D．Derivatives of 3H-Phenanthr[9,10-d][1,2]oxazine339

E．Furazano[3,4-d][1,2]oxazine339

Chapter ⅩⅣ．The 1,3-Oxazines341

Ⅰ．Monocyclic Systems341

Ⅱ．Condensed Systems350

A．1,3-Benzoxazines351

B．3,1-Benzoxazines359

C．Pyrido[1,2-b][1,3]oxazine366

D．2-Naphth[2,3-e][1,3]oxazine366

E．4-Naphth[2,3-d][1,3]oxazine366

F．2-Naphth[2,1-e][1,3]oxazine and 1-Naphth[1,2-e][1,3]oxazine366

G．4-Naphth[1,2-d][1,3]oxazine366

H．1-Naphth[2,1-d][1,3]oxazine366

I．Naphth[1,8][1,3]oxazine367

J．4H-Anthr[1,2-d][1,3]oxazine367

K．Naphthaceno[5,6-de][1,3]oxazine367

L．2-Pyrido[3,2-h][1,3]benzoxazine367

M．4-Pyrido[2,3-h][3,1]benzoxazine367

N．Thianaphthenooxazines368

O．5-Isoindolo[2．1-a][3,1]berzoxazine368

P．Pyrazolobenzoxazines368

Q．Pyrazolo[4,3-e][1,3]oxazine369

R．Isoxazolo[4,5-e][1,3]oxazine369

S．Indazolylbenzoic Acid369

T．Indolo[3,2-d][1,3]oxazine or Indolo[2,3-d][1,3]oxazinc370

U．3,4-[Indolo(1,2)]-5,6[indolo(3,2)]-△5-dihydro-1,3-oxazine370

V．4H,5H-Pyrano[3,4-e][1,3]oxazine370

W．1,3-Oxazino[2,3-e]pyrazole371

Chapter ⅩⅤ．The 1,4-Oxazlnes377

Ⅰ．Monocyclic Systems377

Ⅱ．Condensed Systems394

A．1,4-Benzoxazines394

B．5,8-Methano-1,4-benzoxazine397

C．8-Oxa-3-azabicyclo[3,2,1]octane397

D．3-Oxa-8-azabicyclo[3,2,1]octane(Morphopyrrolidine)and 3-Oxa-9-azabicyclo[3,3,1]nonane(Morphopiperidine)398

E．Cyclopenta[b][1,4]benzoxzzine398

F．4H-Naphth[2,3][1,4]oxazine398

G．1H-Naphth[2,1][1,4]oxazine399

H．2H-Naphth[1,2][1,4]oxazine399

I．1H-Anthr[2,1][1,4]oxazine400

J．12H-Acenaphtho[1,2-b][1,4]benzoxazine400

K．3-Methyl-6,8-dioxa-3-azabicyclo[3,2,1]octane400

L．3-Oxa-6-thi-8-azabicyclo[3,2,1]octane400

M．Thiazolooxazines401

N．1H-Pyrrolo[2,1-c][1,4]oxazine401

O．Pyrrolo[3,4-b][1,4]oxazine401

P．Pyrazolo[3,4-b][1,4]oxazine401

Q．5H-[1,4]-Oxazino[2,3-d]pyrimidine402

R．Triazolobenzoxazine402

S．Imidazo[b][1,4]benzoxazine402

T．Imidazo[f][1,4]benzoxazine402

U．5H-Pyrido[1,2,3-de][l,4]benzoxazine403

V．Pyrido[3,2-b][1,4]benzoxazine,Pyrido[4,3-b][1,4]benzoxazinc and Pyrido[3,4-b][1,4]benzoxazine403

W．2H-[1,4]-Oxazino[b]phenazine403

X．7H-[1,4]-Oxazino[de]phenazine403

Y．[1,4]Benzoxazino[3,2-b][1,4]benzoxazine(Diphendioxazine)404

Z．11H-Quinoxalo[2,3-b][1,4]benzoxazine(Diphenazineoxazine)404

A′．5H-6-Oxa-12,14-dithia-5,7,13-triazapentacene(Dibenzothi-azoxine)404

B′．1H-[1,4]-Oxazino[4,3-a]indole404

C′．Pyrimidino[4,5-b][1,4]benzoxazine405

Ⅲ．Condensed Systems-Phenoxazines and Allied Compounds407

A．Phenoxazines408

B．Phenoxazones,Phenoxazines,and their Salts:the Phenoxa-zonium and Phenazoxonium Compounds414

C．Triphendioxazine and Related Compounds432

D．Trinaphthodioxazine434

E．Quinoxalo[2,3-b]phenoxazines,triphenazineoxazincs434

F．7H-Benzo[a][1,4]benzoxazino[3,2-i]phenazine435

G．Pyrido[3,2-a]phenazoxonium Salts435

H．Chrysophenoxazine435

Chapter ⅩⅥ．Systems of Two Oxygen Atoms and One Nitrogen Atom:the Dioxazines443

Ⅰ．Monocyclic Systems443

Ⅱ．Condensed Systems444

Chapter ⅩⅦ．Systems of Three Oxygen Atoms and One Nitrogen Atom445

Ⅰ．Monocyclic Systems445

Ⅱ．Condensed Systems445

Chapter ⅩⅧ．Systems of One Oxygen Atom and Two Nitrogen Atoms:the Oxadiazines447

Ⅰ．Monocyclic Systems447

A．1,2,4,4H-and 1,2,4,6H-Oxadiazines447

B．1,2,5-Oxadiazines448

C．1,2,6-Oxadiazines449

D．1,3,4-Oxadiazines450

E．1,3,5-Oxadiazines452

Ⅱ．Condensed Systems454

A．The Benzoxadiazines454

B．1H-Anthr[2,3][1,3,4]oxadiazine456

C．2H-Phenanthr[9,10][1,3,4]oxadiazine456

D．8H-Acenaphth[1,2][1,3,4]oxadiazine456

E．1,3,4-Oxadiazino[6,5-b]indole456

F．Benzopyrano-oxadiazines457

G．Anhydride of 7,9-Bis-hydroxymethyleneuric Acid457

H．5H-Pyrazolo[3,2-c][2,1,4]benzoxadiazine457

I．Pyrid[1,2-c][1,3,5]oxadiazine458

Chapter ⅩⅨ．Systems of One Oxygen Atom and Three Nitrogen Atoms459

Ⅰ．Monocyclic Systems459

Ⅱ．Condensed Systems460

Chapter ⅩⅩ．Systems of Two Oxygen Atoms and Two Nitrogen Atoms461

Ⅰ．Monocyclic Systems461

Ⅱ．Condensed Systems461

Chapter ⅩⅪ．Systems of More Than Four Hetero Atoms,Nitrogen and Oxygen463

Subject Index467

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摘要：本文以“FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGEN.pdf电子书版文档下载”为中心，详细阐述了该文档在五元和六元含氮氧化合物研究领域的价值、内容结构、应用前景以及下载方法，旨在为相关领域的研究者和学习者提供有益的参考。

1、研究价值

五元和六元含氮氧化合物在化学、材料科学、药物化学等领域具有广泛的应用前景。该文档系统地介绍了这一类化合物的性质、合成方法、结构特征及其在各个领域的应用，对于推动相关领域的研究具有重要意义。

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2、内容结构

“FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGEN.pdf电子书版文档下载”分为以下几个部分：引言、五元含氮氧化合物、六元含氮氧化合物、应用领域、合成方法、结论。

引言部分简要介绍了五元和六元含氮氧化合物的背景知识，为后续内容奠定了基础。五元和六元含氮氧化合物部分详细阐述了这一类化合物的结构特征、性质、合成方法等。应用领域部分介绍了五元和六元含氮氧化合物在各个领域的应用实例。合成方法部分详细介绍了多种合成途径，为研究者提供了丰富的合成思路。结论部分总结了全文的主要观点，并对未来研究方向进行了展望。

文档结构清晰，内容丰富，便于读者快速了解五元和六元含氮氧化合物的研究现状和发展趋势。

3、应用前景

五元和六元含氮氧化合物在材料科学、药物化学、催化等领域具有广泛的应用前景。以下列举几个典型应用实例：

在材料科学领域，五元和六元含氮氧化合物可用于制备新型功能材料，如导电材料、磁性材料、光催化材料等。在药物化学领域，这类化合物可作为先导化合物，用于开发新型药物。在催化领域，五元和六元含氮氧化合物可作为催化剂或催化剂前体，提高催化效率。

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4、下载方法

“FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGEN.pdf电子书版文档下载”可通过以下途径获取：

1. 访问相关学术网站，如CNKI、万方数据等，搜索文档标题，下载电子版。

2. 联系文档作者或所在单位，获取文档电子版。

3. 在线购买电子书，如亚马逊、京东等电商平台。

下载文档后，读者可结合自身需求进行深入研究。

总结：

“FIVE-AND SIX-MEMBERED COMPOUNDS WITH NITROGEN AND OXYGEN.pdf电子书版文档下载”在五元和六元含氮氧化合物研究领域具有较高的价值。通过对该文档的详细阐述，本文旨在为相关领域的研究者和学习者提供有益的参考。随着科学技术的不断发展，五元和六元含氮氧化合物的研究将取得更多突破，为人类社会带来更多福祉。

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